Three Ways We Could Improve Lithium-Ion Batteries

on May 25, 2020
Energy-Storage-News

Driven by an ever-increasing world population as well as global economic growth, our energy needs have been rising rapidly, peaking 113,000TWh in 2017 according to the International Energy Agency. The impact of this growth on the environment and well-being of society is becoming more apparent, intensifying the need to decarbonise the transportation and power generation sectors – the two highest polluting sectors in the European Union (EU).

Electromobility has become the prevalent solution for the decarbonisation of the transportation sector, with sales of EVs increasing by 60% in the last two years. In the power generation sector meanwhile, the harvesting of wind and solar is gaining pace, with a quarter of global electricity coming from renewable energy sources.

For these solutions to reach their full potential, they need to be coupled with efficient energy storage technologies. The performance of lithium-ion (Li-ion) batteries has increased tremendously as a result of significant investments in R&D; energy density has tripled since 2008, while cost has reduced by close to 85%. Still, further research is needed to decrease levelised cost of energy (LCOE), and ensure that the production and use of batteries does not generate a negative impact on the environment.

  1. Find alternatives to scarce electrode materials to improve energy density and decrease the impact on the environment and society
    Today’s batteries include REE (Rare Earth Elements), CRM (Critical Raw Materials), and other “sensitive” materials. The most crucial elements are perhaps Cobalt (Co), Nickel (Ni), Manganese (Mn), and Lithium (Li), due to their importance in the battery’s final electrochemical performance.

The EU’s Joint Research Centre estimates that demand for these materials will grow by up to 2,500% from 2015 to 2030, creating a scarcity issue. The fact that most such elements are unevenly distributed around the world does not make things easier either; one-third of nickel and lithium used in batteries globally are mined in China and Chile respectively, while two-thirds of cobalt supplies are sourced from the Democratic Republic of Congo, according to the European Commission. This creates significant supply chain risks and contributes to the huge short- and long-term price volatility. Adding to that is the questionable impact on the environment and society from the sourcing of such materials, with most infamously, the mining of cobalt in the Democratic Republic of Congo using artisanal mines and child labour.

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Fractal Energy Storage ConsultantsThree Ways We Could Improve Lithium-Ion Batteries

German Research Pinpoints Safety Risk for Lithium-ion Batteries

on May 15, 2020

Sydney, Australia, May 15, 2020 – (ABN Newswire) – Ground breaking research recently completed by a leading German battery technology institute has identified a previously unrecognised contamination and safety risk for lithium-ion batteries – the use of lower purity (grade) alumina in battery cell manufacture.

The Fraunhofer Institute for Ceramic Technologies and Systems IKTS in Dresden Germany, recently completed test work that has the potential to rock the lithium-ion battery industry.

Globally, lithium-ion battery production is rapidly expanding to meet the burgeoning demand from electric vehicles (EV’s) and portable electronic devices. The Fraunhofer ITKS research was triggered because a significant part of the industry, including those that supply EV batteries, are turning to cheaper substitutes such as low grade alumina and boehmite as the coating material on battery separator sheets and composite separators. However, this hot-off-the-press German research brings into question the safety of using lower quality separator coating materials.

A lithium-ion battery stores then releases power by lithium ions moving between the battery cathode and anode, representing the charge and visa-versa discharge cycles. Separating the cathode and anode within the battery is a liquid electrolyte and a thin polymer sheet through which lithium ions pass – a separator sheet. The composition of these polymer separator sheets has evolved over time in parallel with increases in battery energy density and faster charging requirements. Now separator sheets are mostly coated with thin layers of alumina powder to maintain separator integrity under the ever-increasing operating temperatures of modern high-energy lithium-ion batteries.

Wisely it would seem, the lithium-ion battery industry initially adopted high grade 4N alumina (99.99%) as the standard coating material for separator sheets, especially where battery safety was paramount – such as in EV’s. The scientific tests recently completed by the Fraunhofer IKTS plainly vindicate the initial choice of 4N alumina by the battery industry. In its tests, the Institute exposed various commercially available lower grades of alumina / boehmite powders to lithium battery electrolyte solution under controlled battery type conditions. What was observed was extremely concerning – the severe leaching of sodium from the lower grade alumina’s into the organic electrolyte solution, which resulted in significant electrolyte contamination.

Specifically, the research reported that in its test of 3N alumina (99.9% alumina) the sodium content within the electrolyte solution rose from an acceptable 0.5 ppm up to a potentially catastrophic level of 40 ppm (an 80-fold increase). Similar leaching was observed for boehmite (99.7% alumina), where the level of sodium in the electrolyte jumped 20-fold. As a base line, sodium leaching from 4N alumina (99.99%) into the electrolyte is negligible, as there is virtually no sodium present in the 4N product.

Sodium contamination is one of the major no no’s for anywhere within a lithium-ion battery. Sodium can dramatically reduce battery discharge capacity and adversely affect the reactivity of lithium ions. When too much sodium is present in a battery’s organic electrolyte solution, the movement of lithium ions is hindered and the discharge capacity is rapidly reduced; the performance of the battery is compromised. Lithium-ion battery end-users such as EV assemblers or high-end portable electric device manufactures would never accept a battery with an electrolyte solution containing 40ppm sodium – yet it would seem that this is where they are set to end up if 3N alumina / boehmite is adopted by industry as a coating on battery separator sheets.

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Fractal Energy Storage ConsultantsGerman Research Pinpoints Safety Risk for Lithium-ion Batteries

‘Important to Explore Alternatives’ to Lithium-Ion, Shell-NREL Accelerator Says

on May 5, 2020
Energy-Storage-News

A collaboration between the innovation arm of fossil fuel company Shell and the US National Renewable Energy Laboratory (NREL) selected the maker of an organic flow battery among a group of “startups with the potential to dramatically alter the future global energy landscape”.

Adam Duran, programme director at Shell GameChanger Accelerator Powered by NREL (styled as CGxN), spoke with Energy-Storage.news about the selection of Jolt Energy Storage as one of three startups selected to receive technical and capital resource assistance to accelerate commercialisation of their products, and de-risking investment somewhat.

Duran said the three companies, the third tranche of selected cohorts, “represents startups that are increasing efficiency of solar and energy storage technologies and standardising manufacturing processes at a lower cost than available solutions,” with the overall accelerator programme focusing on “accelerating the commercialisation of disruptive, novel technologies”.

Beechwood, Michigan-headquartered Jolt makes flow batteries “with the same large-scale storage capabilities as lithium-ion, but at a lower cost,” a press release sent out by GCxN said. The devices use organic compounds for electrolytes and claim an energy density around four times that of vanadium redox flow batteries.

Selected alongside Jolt and its redox flow energy storage batteries were BluDot Photonics, which is attempting to create cost-effective and scalable solar cells using perovskite and Icarus RT, which is making a hybrid solar-thermal photovoltaic system that recycles “waste heat” from solar panels.

“As renewables adoption increases over time, the need for large-scale energy storage technologies will continue to grow,” NREL staffer Duran said, in explaining Jolt Energy’s selection.

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Fractal Energy Storage Consultants‘Important to Explore Alternatives’ to Lithium-Ion, Shell-NREL Accelerator Says

Diamond Nanothreads Could Store Thrice The Energy of Li-ion Batteries

on April 21, 2020

Satisfying the energy needs of a growing population in a sustainable way calls for some inventive solutions, and ones not necessarily limited to the confines of battery chemistry. Solutions to storing energy in mechanical systems instead could include huge towers of swinging blocks or, at the other end of the spectrum, tiny bundles of ultra-fine carbon threads, as a new study from Australia’s Queensland University of Technology has shown.

The researchers behind the study describe their proposed energy storage system as a diamond nanothread bundle, which are tiny structures that material scientists have been exploring for some time due to their unique physical properties. These bundles consist of very fine one-dimensional carbon threads, which can be twisted or stretched as a way of storing mechanical energy.

“Similar to a compressed coil or children’s wind-up toy, energy can be released as the twisted bundle unravels,” says study author Dr Haifei Zhan. “If you can make a system to control the power supplied by the nanothread bundle it would be a safer and more stable energy storage solution for many applications.”

Zhan and his team conducted computer modeling to investigate the energy density of a hypothetical diamond nanothread bundle. According to the results, these systems could store 1.76 MJ per kilogram, which is around four to five orders higher than a steel spring of the same mass, and up to three times that of lithium-ion batteries.

While this superior energy density is a huge incentive to develop a system like this, its safety another. Because it doesn’t involve the types of electrochemical reactions that take place in lithium ion batteries, it avoids the risk of leaks, explosions or simple chemical failure.

“At high temperatures chemical storage systems can explode or can become non-responsive at low temperatures,” says Zhan. “These can also leak upon failure, causing chemical pollution. “Mechanical energy storage systems don’t have these risks so make them more suited to potential applications within the human body.”

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Fractal Energy Storage ConsultantsDiamond Nanothreads Could Store Thrice The Energy of Li-ion Batteries

Looking Back Over Lithium

on April 10, 2020
PV-Magazine

Since scientists demonstrated the first rechargeable lithium-ion battery in 1976, the technology has proven its world-changing potential in the electronics industry. But even as applications in electric vehicles and stationary storage record massive growth, the technology has issues to overcome and scientists the world over are hard at work on integrating new materials and pushing more performance out of batteries still based on the concepts illustrated by scientists almost half a century ago.

And looking back over these developments can be valuable in informing the future direction of research. Arumugam Manthiram has been a professor at the University of Texas at Austin for 20 years, and has also worked on lithium-ion technology alongside Nobel Prize-winning scientist John Goodenough. In a review paper published in Nature Communications, Manthiram delves into the history of lithium-ion technology and examines the issues influencing current research into new battery concepts.

“Cost and sustainability are becoming critical as we move forward with large-scale deployment of lithium-ion batteries,” says Manthiram. “Also, there is an appetite to increase the energy density beyond the current level to keep up with the advances in portable electronic devices and enhance the driving range of electric vehicles.”

Big three

The paper outlines three major discoveries that brought about the lithium-ion batteries we see on the market today.

The first demonstration of a rechargeable battery with a lithium-metal anode and titanium sulfide cathode by M. Stanley Whittingham at Exxon in the 1970s provided proof of concept for recent advances in the understanding of intercalation chemistry. This battery was hampered by low voltage and energy density, as well as dendrite growth on the lithium-metal anode – a problem scientists today are still working to solve.

Next Manthiram focuses on work by John Goodenough’s group in the 1980s, which was awarded the 2019 Nobel Prize for Chemistry. This concerns the design of oxide cathodes, which allowed for increased voltage in the battery. Goodenough’s group also divided oxide cathodes into three classes (layered, spinel and polyanion), which remain the only practical cathode types to this day, and serve as the basis for future developments.

Finally, further work by Goodenough’s group in the 1980s, led by visiting researcher Koichi Mizushima, provided the first demonstration of a lithium battery with a carbon anode and lithium cobalt oxide cathode. It represented the first time the technology overcame safety and energy density issues, and was presented as something ready for commercialization.

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Fractal Energy Storage ConsultantsLooking Back Over Lithium

Panasonic To Suspend Battery Production at Tesla Joint Venture in Nevada Due to Coronavirus

on March 23, 2020
Nasdaq

TOKYO, March 21 (Reuters) – Panasonic Corp 6752.T said on Saturday it will temporarily suspend production at its battery joint venture with U.S. electric carmaker Tesla Inc TSLA.O in Nevada because of the coronavirus outbreak.

The Japanese electronics company, which supplies battery cells for Tesla’s electric vehicles, will scale down operations at so-called Gigafactory 1 early next week before closing it for 14 days, Panasonic said in an emailed statement.

A Panasonic spokeswoman declined to comment on how the suspension would affect Tesla, which produces battery packs using Panasonic cells at the Nevada plant.

Tesla on Thursday said its operations at the Nevada battery plant would continue, while it would suspend production at its San Francisco Bay Area vehicle factory on March 24.

Panasonic said Nevada plant employees affected by the shutdown will receive full pay and benefits for the entire period. During the closure, the facility will undergo intensive cleaning, it said in the statement.

TechCrunch, which first reported the planned suspension, said Panasonic has about 3,500 employees at the Nevada plant.

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Fractal Energy Storage ConsultantsPanasonic To Suspend Battery Production at Tesla Joint Venture in Nevada Due to Coronavirus

Lithium Ion Batteries to Top Energy Storage Tech: Study

on March 11, 2020
TandD-World

Lithium ion batteries will be the fastest growing energy storage technology, with annual growth expected to reach more than 28 GW by 2028. The technology is expected to account for 85% of newly installed energy storage capacity, according to analysis by Navigant Research.

A new report from Navigant Research provides a database of global energy storage projects along with a regional analysis of technology choice, capacity, and market share for deployed projects and projects in the pipeline.

Regulatory policy, government incentives, deployment mandates, grid modernization programs, and declining technology costs created market conditions in which hundreds of energy storage projects were deployed around the world between 2018 and 2019. In this growing market, Lithium ion (Li-ion) batteries have maintained a prominent place in the transformation of the power grid.

“Although pumped hydro storage (PHS) still accounts for 96% of installed energy storage capacity worldwide, Li-ion is the choice technology among project developers and system integrators,” says Ricardo F. Rodriguez, research analyst with Navigant Research. “The technology is expected to account for 85% of newly installed energy capacity.”

In addition to the growth of Li-ion, three types of storage projects typified deployments across the globe in 4Q 2019. According to the report, these include commercial and industrial applications located behind-the-meter (BTM), utility-scale battery storage projects that replace gas peaker plants, and utility-scale storage projects co-located at large solar PV or wind generation facilities.

The report, Energy Storage Tracker 4Q19, provides a comprehensive resource of global energy storage projects. The Tracker includes a database of 2,169 projects (encompassing at least 64,664 individual systems) and tracks the country, region, market segment, capacity, status, technology vendor, systems integrator, applications, funding, investment, and key milestones of each project.

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Fractal Energy Storage ConsultantsLithium Ion Batteries to Top Energy Storage Tech: Study

Lithium Recycling Goes Commercial To Meet ‘Unprecedented Phase of the Market’

on February 3, 2020
Energy-Storage-News

A new lithium battery recycling facility, established by operator Li-Cycle on a commercial basis at the well-known Eastman Business Park in New York State, answers both a growing need and an opportunity in an “unprecedented phase” of deployment, the company has said.

The Canadian company has previously penned a technical feature article for Energy-Storage.news and PV Tech Power on the science and technology underpinning its two-step process for recycling, claiming that 80% to 100% of battery recycling is possible through mechanical size reduction (shredding packs and cells) and then recovering materials through a hydrometallurgical process. Li-Cycle announced its first commercial shipment of recycled lithium battery materials to a customer at the beginning of this year.

Eastman Business Park in Rochester, New York, is also host to a number of other battery industry operations, including Kodak’s battery production centre. Li-Cycle representatives said via email that the announced facility will be a “spoke” of the companies operations (as opposed to a “hub”), with capacity to process 5,000 tonnes of spent lithium-ion batteries per year.

“The ‘Spoke’ technology transforms lithium-ion batteries into an inert, non-hazardous intermediate product consisting of the electrode material, while separating plastics and other metals contained in the battery for further downstream recycling by third parties,” the company’s representatives said in an exclusive commentary sent to Energy-Storage.news this week.

‘First step to addressing mass market global opportunity’
According to Li-Cycle, the Monroe County, Rochester, site location offers several strategic advantages including EBP’s on-site analytical labs, with trade association / technology accelerator NY BEST also hosting some R&D, testing and innovation facilities at the park. Being in New York also gives good access to battery materials from EVs, portable electronics and energy storage from a broad area of the US, from the Midwest through to the Northeast.

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Fractal Energy Storage ConsultantsLithium Recycling Goes Commercial To Meet ‘Unprecedented Phase of the Market’

Lithium-Ion Startups Attract Lion’s Share Of Energy Storage Venture Capital in 2019

on January 24, 2020

Venture capital firms poured nearly $2 billion into battery storage companies in 2019.

The new report by Mercom Capital keeps tabs on how publicly known VC funding was allocated to energy storage, smart grid and energy efficiency companies. These transactions would include mergers and acquisition activity, as well.

Mercom reported that battery storage attracted $1.7 billion worth of investment last year, compared to $300 million for smart grid companies and $298 million for energy efficiency entities.

The global funding picture include venture capital, private equity and corporate VC investments. The total for the combined storage, smart grid and efficiency sectors was down 22 percent compared with the $3.9 billion moved in 2018, according to Mercom.

Battery storage, however, doubled year over year even though the $1.7 billion was spread out over fewer deals than in 2018. The increased investment was buoyed by Volkswagen’s $1 billion capitalization in Northvolt, a battery startup founded by two former Tesla executives, in the second quarter.

Lithium-ion battery technology companies accounted for 80 percent of the energy storage VC picture. Venture capital also put money in other storage technologies such as flow batteries, fuel cells, solid-state and zinc-air, among others.

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Fractal Energy Storage ConsultantsLithium-Ion Startups Attract Lion’s Share Of Energy Storage Venture Capital in 2019

Energy Storage Association Commends Move To Lower Tariffs on Lithium-Ion Batteries

on January 20, 2020

The U.S. Trade Representative lowered tariffs on Chinese lithium-ion batteries to 7.5 percent from 15 percent.

The new rate goes into effect on Feb. 14. The change in the tariff will ease the adverse economic effects on grid energy storage deployments in the country.

The U.S. Energy Storage Association (ESA) applauded the move but believes more is necessary.

“This week’s action demonstrates movement in the right direction; however, ESA looks forward to timely and full removal of the tariffs,” ESA CEO Kelly Speakes-Backman said.

ESA has concerns about any tariffs on lithium-ion battery imports. Organization officials say the tariffs are inconsistent with the federal government’s efforts to encourage growth in storage deployment and create jobs.

“ESA and its members continue to call on the U.S. Trade Representative for the full removal of the tariffs on grid energy storage components, due to storage’s critical role in improving electric system resilience, energy security, and job creation. We look forward to working with the Administration to remove impediments to America’s efforts to modernize its electric system,” Speakes-Backman added.

ESA is the national trade association for the energy storage industry. With more than 190 members, ESA represents independent power producers, electric utilities, energy service companies, financiers, insurers, law firms, installers, manufacturers, component suppliers and integrators involved in deploying energy storage systems around the globe.

More information on the impacts of import tariffs on the American energy grid infrastructure can be found on their web site, www.energystorage.org.

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Fractal Energy Storage ConsultantsEnergy Storage Association Commends Move To Lower Tariffs on Lithium-Ion Batteries